Needle-less electrospinning appeared in the early 1970s, when Simm and coworkers filed a patent on using an annular electrode to electrostatically spin fibers for filtration appli cations. Next, Lukas et al. investigated the self-organization of charged jets initiated from the open free-liquid surface in the electrospinning process. Lin and colleagues developed a rotating spiral coil spinneret, which had a high fiber production rate with well-controlled fiber morphology. Liu et al. electrospun nanofibers by blowing air into the polymer solution. The bubbles generated assisted in jet initiation. Since 2008, growing research has been devoted to needle-less electrospinning. Research publications have been increasing constantly over the years. Over 100 articles about needle-less electrospinning or free-surface electrospinning have been published since 2007. The publication number between 2014 and 2016 was approximately 10 times more than that of 2007e2013 (Fig. 7.2A). Research is widespread in many countries. China, Australia, and the Czech Republic take about 80% of publications, followed by the United States, Germany, and England (Fig. 7.2B).
Foshan Lepton Precision M&C Tech Co.,Ltd(QINGZI NANO)is a national high-tech enterprise covering R & D, manufacturing, sales and technical services. And it’s a reputable manufacturer from China which specializes in electrospinning technology as well as biological 3D printing technology, electrospray printing and nanofibers materials equipment.
2019年8月21日星期三
2019年6月29日星期六
Lab Scale Electrospinning Machine E03-001 Sold to The University of Waterloo In Canada
Features:
Desktop style, small size;
Function integrated, professional;
Superior performance, CE/FCC certification;
4.3 inch numerical screen, simple and clean integration operating system;
Highly cost effective, elegant appearance;
Tool machine, affordable;
Parameters:
Spinning voltage: 0-30kv;
Both roller and panel collector;
Nozzle reciprocating motion breadth: 150mm
Dimension: 600*600*800mm
Net weight: 47.46KG
2019年6月27日星期四
2019年6月25日星期二
Nanomaterial Spraying Machine
Introduction
Nanomaterial spraying technology is based on electrostatic, ultrasonic, gas field for fine spraying of low-viscosity materials, solving the agglomeration problem in the use of nanoparticles. With nano-scale microsphere spraying, the technology can be applied to the preparation of fuel cell proton exchange membranes, electrode catalytic materials, battery separators, heat exchange membranes, quantum materials, etc.
Features
- Feeding method: injection pump;
- Applicable solution viscosity: ≤30cps;
- Environment temperature range: room temp up to 60±3℃ adjustable;
- Environment humidity range: room humidity down to 40%±5%RH adjustable;
- Independent R&D.
2019年6月18日星期二
PROFESSIONAL MICRO/NANO 3D PRINTER
Features
- Desktop style, small size;
- Maximum printing speed: 300mm/s;
- High voltage power supply: 0-10KV adjustable;
- Optional: melt nozzle; precision injection pump;
- Opening mechanical structure, easy to self-assembled and disassembled, can be applied in maker education;
- Optional dual Y-axis motion system for printing continuously.
2019年5月31日星期五
Morphology of Molecular Assembly
Amphiphilic peptides have a hydrophilic head group and a hydrophobic alkyl tail. The hydrophobic tail helps in aligning the head group to form various secondary, supersecondary, and tertiary conformations. Very thin cylindrical nanofibers (<10-nm diameter) with high aspect ratio, or nano belts, are achieved by a self-assembly of peptide amphiphiles (PAs) under specific solution conditions (pH, ionic strength, and temperature). The 1D nanostructures can interact further among one another, making a 3D network. These 3D network structures make a hydrogel in water. Hydrophobic and electrostatic interactions are the dominating forces in the self-assembly of amphiphilic peptides. The amphiphilic cyclic peptide composed of two b-glucosamino acids and one trans-2-aminocyclohexylcarboxylic acid in formic acid and water (7/3 v/v) makes self-assembled rods and fibers of different dimensions depending upon the solution concentration. A concentration of 1.1 10 5 M provided a rod-shaped assembly of c. 5-nm diameter, which corresponds to a nine-columnar (3 triple bundle) structure (Fig. 4.7A). By increasing the peptide concentration to 1.1 10 4 M, a uniform fibrous assembly of c. 15 nm in
2019年5月28日星期二
Nano-microfiber Composites For Filtration
Nanofibers prepared by molecular self-assembly are in general not self-supporting and therefore require stabilizing scaffold structures. In fact, a lot of research in the past has been done with su pramolecular self-assembly of molecules forming a network of nanofibers used as organo/hydro gelators. But efforts to use them as a self-standing membrane or as free fibers were not strong. Therefore, the self-assembly of trisamides was also tried on a substrate, i.e., other microfiber non wovens, leading to microenanofiber composites (Fig. 4.4) used for filtration (Weiss et al., 2016).
2019年4月29日星期一
Polymer/Carbon Nanotube Composite Nanofibers
To improve the compatibility between CNTs and polymers, the surface functionalization of CNTs has been developed (Kharaziha et al., 2014; Molnar et al., 2008; Ra et al., 2005; Mazinani et al., 2009; Yee et al., 2012; Subagia et al., 2014; Diouri et al., 2014). For instance, Kharaziha et al. established a simple strategy to prepare electrospun gelatin/CNT composite nanofibers by using carboxyl acid groupemodified CNTs, and the well-dispersed CNTs aligned along the fibrous axis could be observed (Fig. 3.15B). This work demonstrated CNTs as a component of tough and flexible scaffolds with outstanding electrical properties (Kharaziha et al., 2014). Molnar et al. (2008) synthesized PVA/CNT composite nanofibers with diverse types of CNTs and different functional groups via electrospinning. Furthermore, other synthetic methods such as electrospinning combined with electrospraying and a surface adsorption approach have been developed as well (Xuyen et al., 2009; Kim et al., 2006b; Vaisman et al., 2007; Dai et al., 2011; Rana and Cho, 2011).
2019年4月28日星期日
Polymer/Fe3O4 Composite Nanofibers
Magnetic NPs have been receiving increased attention with the rapid development of nanotechnology.Among them, Fe3O4 NPs have caused widespread interest owing to their high superparamagnetism as well as facile preparation. Their easy oxidation and resulting decline in magnetic property is a problem, however, which is effectively solved by the dispersion of Fe3O4 NPs in polymer nanofibers. The simplest way to prepare polymer/Fe3O4 composite nanofibers is to disperse Fe3O4 NPs in the polymer solution and subsequently carry out the electrospinning process. Xin et al. successfully fabricated poly(p-phenylene vinylene)/Fe3O4 composite nanofibers via electrospinning of a precursor solution and subsequent thermal conversion (Fig. 3.14A). In addition, the aligned nanofibers can be obtained by employing two parallel magnets as the collector. A variety of polymer/ Fe3O4 composite nanofibers, including PAN/Fe3O4 composite nanofibers, gelatin/Fe3O4 composite nanofibers, etc., have been reported by means of a similar method, and their potential applications in various fields have been studied as well.
2019年4月25日星期四
METAL NANOFIBERS
Metal nanomaterials possess unique physical and chemical properties and certain special functions compared with many other functional nanomaterials. Electrospun metal nanofibers show excellent thermal stability and conductivity and possess potential applications in photoelectricity, sensors, high temperature filtration, and other fields (Bognitzki et al., 2006; Hsu et al., 2012; Shao et al., 2011; Zhang et al., 2016c; Wu et al., 2007; Hansen et al., 2012). In 2006, Bognitzki et al. successfully prepared Cu nanofibers through a strategy involving an electrospinning technique followed by calcination in an air and H2 atmosphere. It was the first time that electrospun Cu nanofibers had been reported (Bognitzki et al., 2006). Later, Hsu et al. coated a passivation layer on electrospun Cu nanofibers (Fig. 3.12A). The results showed that the treated sample possessed superior durability as well as resistance over the bare Cu nanofibers. It is anticipated that the product can be applied as stable transparent electrodes (Hsu et al., 2012).
2019年4月20日星期六
ZnO Nanofibers
The potential applications of electrospun ZnO nanofibers have been widely studied. For example, Zhang et al. (2009b) fabricated uniform ZnO hollow nanofibers and investigated their gas-sensing activity against ethanol. Similarly, Wei et al. (2011b) studied the performance of electrospun ZnO hollow fibers as an acetone gas sensor. Katoch et al. (2016a,b) measured the influence of hole diameter as well as crystallinity in ZnO hollow nanofibers on the gas-sensing property.
2019年4月17日星期三
FexOy (Iron Oxide) Nanofibers
It is generally known that iron oxides mainly contain Fe2O3 and Fe3O4. Fe2O3 is stable in air, and possesses potential applications in adsorption, sensors, electrochemical catalysis, and other fields. On the other hand, Fe3O4 is a typical kind of magnetic material, which can be applied in magnetofluid as well as magnetic recording materials. Fe2O3 nanofibers with uniform structure can be easily prepared via an electrospinning technique followed by a calcination treatment (Fig. 3.6A). For example, Gao et al. prepared hollow a-Fe2O3 nanofibers via such a strategy and developed their potential in dye adsorption. Similarly, Nalbandian et al. found that electrospun Fe2O3 nanofibers possess promising prospects in heavy metal removal. Guo et al. studied the effect of the structure of electrospun Fe2O3 nanotubes on gas sensing; the results indicated that porous a-Fe2O3 nanotubes exhibited remarkably enhanced performance for acetone sensing over hollow a-Fe2O3 nanotubes. g-Fe2O3 nanofibers have also been successfully synthesized and their properties as acetone gas sensors have been found as well.
2019年4月16日星期二
Single-Component Synthetic Polymer Nanofibers
Herein, we divide the synthetic polymers into several species. Among them, organic solvent-soluble polymers have been greatly developed, for example, electrospun polystyrene (PS) nanofibers have been prepared from different solvent systems (Fig. 3.5A). DMF, tetrahydrofuran, and their mixtures are the most commonly used solvents (Lin et al., 2010; Nitanan et al., 2012). Electrospinning of polyacrylonitrile (PAN) nanofibers also employs DMF as solvent (Fig. 3.5B), and they are a kind of excellent precursor for the fabrication of carbon nanofibers, which have been widely studied (Fen nessey and Farris, 2004; Gu et al., 2005). Polymethylmethacrylate (PMMA) is another familiar synthetic polymer; electrospun PMMA nanofibers as well as blended fibers have been developed for more than 10 years (Fig. 3.5C) (Ji et al., 2008; Carrizales et al., 2008).
2019年4月8日星期一
Near Field Direct Writing Electrospinning Equipment M08
- Printing resolation less than 50nm;
- Nanofiber highly oriented and controllable;
- International R & D team pioneering technology;
- Exclusive patented technology;
- Micro nano manufacture excellent tools
Near Electrospinning Technology Classification
Solution Near-field Electrospinning
Solution near-field electrospinning process, the printing material is prepared into a solution, and using electrostatic field print orientation nanofibers. It can produce a fiber orientation controllable fiber diameter range is 50nm-20μm, the solution electrospun near-field have more suitable materials.
Melt near-field electrospinning
Melt Near-field electrospinning process, the printed material is heated and melted, assisted with the electrostatic field, fibers with a diameter range of 500nm-50μm can be prepared, high 3D printing capability, very suitable for producing three-dimensional biological tissue engineering scaffolds.
Near field electrospinning equipment parameters
- High voltage power supply: 0-30kv, adjustable;
- Solution spinning nozzle: solution supply volume at least 10μl/h;
- Melt spinning nozzle: nozzle temperature: 0-300℃, adjustable, precision pneumatic extrusion;
- Printing environment temperature: indoor temperature -50℃, adjustable;
- Collection platform: printing range 150*150mm, platform speed: 0-200mm/s, resolution: 50nm;
- Nozzle height: 0-80mm, adjustable, resolution: 50nm;
- Printable materials: PE0, PVA, PLA, PCL, PLGA, chitosan, sodium alginate, collagen, hydroxyapatite, PVDF and other hundreds of organic or inorganic materials;
- printable user-defined patterns;
- printable 3D structure;
- customizable : temperature controllable collector;
- customizable : multi-nozzle device.
Lab Scale Electrospinning Machine E03-001
Features:
- Desktop style, small size;
- Function integrated, professional;
- Superior performance, CE/FCC certification;
- 4.3 inch numerical screen, simple and clean integration operating system;
- Highly cost effective, elegant appearance;
- Tool machine, affordable;
Parameters:
- Spinning voltage: 0-30kv;
- Both roller and panel collector;
- Nozzle reciprocating motion breadth: 150mm
- Dimension: 600*600*800mm
- Net weight: 47.46KG
2019年4月1日星期一
Multifunctional Nanofiber Electrospinning Equipment E06
Features:
- Temperature and humidity can be control in high precision and high speed;
- Can timing control the experiment;
- Modular design, multifunction;
- Multiple nozzle system;
- Automatic control intake and exhaust;
- Color touch screen, numerical control system;
- Operation is simple and clear.
Parameters:
- High voltage power supply: positive : 0-50kv; negative : 0-30kv;
- Double pump: the smallest solution supply volume is 10μl/h;
- Temperature control: indoor temperature: -70℃, precision: ±1℃;
- Humidity control: indoor humidity: -30%HR, precision: ±3%, humidity control time: 3-5min;
- High precision CNC system, can control experiment time, check the history data etc.;
- Coaxial nozzle, prepare hollow fiber.
2019年3月29日星期五
Electrospinning Micro Nano Biological 3D Printer M08
Features:
- -Printing resolation less than 50nm;
- -Nanofiber highly oriented and controllable;
- - International R & D team pioneering technology;
- - Exclusive patented technology;
- -Micro nano manufacture excellent tools
Near Electrospinning Technology Classification
Solution Near-field Electrospinning
Solution near-field electrospinning process, the printing material is prepared into a solution, and using electrostatic field print orientation nanofibers. It can produce a fiber orientation controllable fiber diameter range is 50nm-20μm, the solution electrospun near-field have more suitable materials.
Melt near-field electrospinning
Melt Near-field electrospinning process, the printed material is heated and melted, assisted with the electrostatic field, fibers with a diameter range of 500nm-50μm can be prepared, high 3D printing capability, very suitable for producing three-dimensional biological tissue engineering scaffolds.
Near field electrospinning equipment parameters
- High voltage power supply: 0-30kv, adjustable;
- Solution spinning nozzle: solution supply volume at least 10μl/h;
- Melt spinning nozzle: nozzle temperature: 0-300℃, adjustable, precision pneumatic extrusion;
- Printing environment temperature: indoor temperature -50℃, adjustable;
- Collection platform: printing range 150*150mm, platform speed: 0-200mm/s, resolution: 50nm;
- Nozzle height: 0-80mm, adjustable, resolution: 50nm;
- Printable materials: PE0, PVA, PLA, PCL, PLGA, chitosan, sodium alginate, collagen, hydroxyapatite, PVDF and other hundreds of organic or inorganic materials;
- printable user-defined patterns;
- printable 3D structure;
- customizable : temperature controllable collector;
- customizable : multi-nozzle device.
Multifunctional Nanofiber Electrospinning Equipment E06
Feature:
- Temperature and humidity can be control in high precision and high speed;
- Can timing control the experiment;
- Modular design, multifunction;
- Multiple nozzle system;
- Automatic control intake and exhaust;
- Color touch screen, numerical control system;
- Operation is simple and clear.
Parameters:
- High voltage power supply: positive : 0-50kv; negative : 0-30kv;
- Double pump: the smallest solution supply volume is 10μl/h;
- Temperature control: indoor temperature: -70℃, precision: ±1℃;
- Humidity control: indoor humidity: -30%HR, precision: ±3%, humidity control time: 3-5min;
- High precision CNC system, can control experiment time, check the history data etc.;
- Coaxial nozzle, prepare hollow fiber.
Lab Scale Electrospinning Machine E03-001
Feature:
- Desktop style, small size;
- Function integrated, professional;
- Superior performance, CE/FCC certification;
- 4.3 inch numerical screen, simple and clean integration operating system;
- Highly cost effective, elegant appearance;
- Tool machine, affordable;
Parameters:
- Spinning voltage: 0-30kv;
- Both roller and panel collector;
- Nozzle reciprocating motion breadth: 150mm
- Dimension: 600*600*800mm
- Net weight: 47.46KG
2019年3月23日星期六
Electrospinning Nanofiber Technology Introduction
Electrospinning technology: electrically charged polymer solution or melt is stretched and refined in high-voltage electrostatic field, accompanied by solvent volatilization or melt solidification, and becomes micro-nano-level fiber, which is deposited on the receiving device to form nanofiber film material with a certain accumulation density.
Features of electrospinning materials: High porosity; Small aperture; High specific surface area.
Application: air filtration, water filtration, battery diaphragm, electrode material, tissue engineering, drug sustained release, heavy metal ion adsorption, gas sensor, waterproof and moisture permeable clothing, catalyst etc.
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